1459205-32-3

Upstream product

• 1459205-22-1 (2S,3S,4R,5S)-6-(tert-butyldiphenylsilyloxy)-3,5-dimethylhexane-2,4-diol 
• 1459205-23-2 (2S,3R,4R,5S)-5-benzyloxy-1-(tert-butyldiphenylsilyloxy)-2,4-dimethylhexan-3-ol 
• 863488-20-4 1-(tert-butyldiphenylsilyloxy)-2-methylpentan-3-one 
• 1459205-31-2 (2R,3R,6S,7R,8S,9S,Z)-1-((S)-4-benzyl-2-thioxothiazolidin-3-yl)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-3-(methoxymethoxy)-2,4,6,8-tetramethyldec-4-en-1-one 
• 1459205-30-1 (2R,3R,6S,7R,8S,9S,Z)-1-((S)-4-benzyl-2-thioxothiazolidin-3-yl)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6,8-tetramethyldec-4-en-1-one 
• 1459205-29-8 (4S,5R,6S,7S,Z)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-enal 
• 1459205-28-7 (4S,5R,6S,7S,Z)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-oct-2-en-1-ol 
• 1459205-27-6 (4S,5R,6S,7S,Z)-ethyl 7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-enoate 
• 1459205-26-5 C₂₁H₃₆O₃Si 
• 1459205-25-4 (2S,3R,4R,5S)-5-benzyloxy-3-(tert-butyldimethylsilyloxy)-2,4-dimethylhexan-1-ol 
• 1459205-24-3 (5R,6S)-5-((2S,3S)-3-(benzyloxy)butan-2-yl)-2,2,3,3,6,10,10-heptamethyl-9,9-diphenyl-4,8-dioxa-3,9-disilaundecane 

Downstream Products

• 1459205-33-4 C₂₉H₅₀O₅Si 
• 1459205-34-5 (5R,8S,9R,Z)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-5-((S)-but-3-en-2-yl)-6,8,11,11,12,12-hexamethyl-2,4,10-trioxa-11-silatridec-6-ene 
• 1459205-37-8 (S)-(2S,3S,4R,5S,8R,9S,Z)-4-(tert-butyldimethylsilyloxy)-8-(methoxymethoxy)-3,5,7,9-tetramethylundeca-6,10-dien-2-yl 2-(tert-butoxycarbonyl(methyl)amino)-3-phenylpropanoate 
• 1459205-38-9 (S)-(2S,3R,4R,5S,8R,9S,Z)-4-hydroxy-8-(methoxymethoxy)-3,5,7,9-tetramethyl-undeca-6,10-dien-2-yl 2-(tert-butoxycarbonyl(methyl)amino)-3-phenylpropanoate 
• 1459205-39-0 (S)-(2S,3S,4R,5S,8R,9S,Z)-4-acetoxy-8-(methoxymethoxy)-3,5,7,9-tetramethylundeca-6,10-dien-2-yl 2-(tert-butoxycarbonyl(methyl)amino)-3-phenylpropanoate 

Relevant academic research and scientific papers

Total synthesis of 5-epi-Torrubiellutin C and its biological evaluation

The total synthesis of 5-epi-Torrubiellutin C is described in a fully stereocontrolled manner and linear sequence involving high yielding steps. The synthetic strategy involves the dicyclohexylboron chloride mediated Paterson's aldol protocol, Horner-Emmo