14595-35-8

Basic information

• Product Name: 2-Butenedioic acid(2E)-, 1,4-dipropyl ester
• Synonyms: 2-Butenedioicacid (2E)-, dipropyl ester (9CI); 2-Butenedioic acid (E)-, dipropyl ester; Fumaric acid, dipropyl ester (6CI,7CI,8CI); Dipropyl fumarate
• CAS NO: 14595-35-8
• Molecular Formula: C₁₀H₁₆O₄
• Molecular Weight: 200.2316
• Mol File: 14595-35-8.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 258.4°Cat760mmHg
• Flash Point: 119.6°C
• Density: 1.031g/cm³
• CAS DataBase Reference: 2-Butenedioic acid(2E)-, 1,4-dipropyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenedioic acid(2E)-, 1,4-dipropyl ester(14595-35-8)
• EPA Substance Registry System: 2-Butenedioic acid(2E)-, 1,4-dipropyl ester(14595-35-8)

Safety Data

• Hazardous Substances Data: 14595-35-8(Hazardous Substances Data)

Upstream product

• 24761-89-5 ⁿpropyl diazoacetate 

Downstream Products

• 1417416-01-3 dipropyl 2-(tosylamino)succinate 
• 1380216-06-7 dipropyl 2-(3-(p-tolylimino)-2-oxoindolin-1-yl)-succinate 
• 1380218-54-1 dipropyl 2-(3-(phenylimino)-2-oxoindolin-1-yl)-succinate 

Relevant articles and documents

Highly chemo- and stereoselective intermolecular coupling of diazoacetates to give cis-olefins by using Grubbs second-generation catalyst

Highly stereoselective formation of cis-2-ene-1,4-diesters by homo- and heterocoupling of α-diazoacetates in the presence of Grubbs second-generation catalyst is demonstrated. The dual reactivity of the catalyst in alkene metathesis and diazocoupling has been exploited in the synthesis of 12-26-membered macrocyclic dienyl dilactones by one-pot carbene dimerisation/ring-closing metathesis.