145950-19-2

Upstream product

• 88196-06-9 syn-1-phenylpropane-1,2-diol 
• 40421-52-1 (1RS,2SR)-1-phenylpropane-1,2-diol 
• 88196-06-9 (1S,2S)-1-phenyl-1,2-propanediol 
• 5364-83-0 1-cyclohexylprop-1-ene 

Downstream Products

• 1001879-49-7 C₁₅H₃₂O₂Si 
• 132538-09-1 (1S,2R)-(-)-1-cyclohexyl-1,2-propanediol 
• 132538-08-0 (1R,2S)-(+)-1-cyclohexyl-1,2-propanediol 
• 145950-29-4 (1S,2R)-1-cyclohexyl-2-iodopropyl acetate 
• 145950-27-2 (1S,2R)-2-bromo-1-cyclohexylpropyl acetate 
• 145950-25-0 (1S,2R)-2-chloro-1-cyclohexylpropyl acetate 
• 145950-30-7 Acetic acid (1S,2R)-2-cyclohexyl-2-iodo-1-methyl-ethyl ester 
• 145950-28-3 Acetic acid (1S,2R)-2-bromo-2-cyclohexyl-1-methyl-ethyl ester 
• 145950-26-1 Acetic acid (1S,2R)-2-chloro-2-cyclohexyl-1-methyl-ethyl ester 
• 145987-14-0 (2S,3S)-(-)-cyclohexyl-3-methyloxirane 

Relevant academic research and scientific papers

Kinetic resolution of 1,2-diols through highly site- and enantioselective catalytic silylation

(Chemical Equation Presented) Resolved to silylate: A chiral silylation catalyst is used for kinetic resolution of three classes of acyclic 1,2-diols. The catalyst differentiates, with excellent precision, between the two hydroxy groups of a substrate. The majority of the diols, obtained in high enantiomeric purity, cannot be accessed with similar stereochemical purity through catalytic asymmetric dihydroxylation.

A Simplified Procedure for the Stereospecific Transformation of 1,2-Diols into Epoxides

A simple, 'one-pot' procedure for the conversion of vicinal diols into epoxides via halohydrin ester intermediates has been developed.This method tolerates a wide range of functionality including acid sensitive functional groups.The transformation proceed