145968-53-2

Upstream product

• 80466-34-8 2,4-hexadienal 
• 151-50-8 potassium cyanide 
• 100-61-8 N-methylaniline 
• 142-83-6 trans,trans-2,4-Hexadienal 

Downstream Products

• 145968-77-0 (2Z)-8-bromo-2-(N-methylanilino)-4-((E)-prop-1-enyl)oct-2-enenitrile 
• 145968-76-9 (2E)-8-bromo-2-(N-methylanilino)-4-((E)-prop-1-enyl)oct-2-enenitrile 
• 145968-79-2 (2Z,5E)-4-(2-bromocyclopent-1-enylmethyl)-2-(N-methylanilino)hepta-2,5-dienenitrile 
• 145968-78-1 (2E,5E)-4-(2-bromocyclopent-1-enylmethyl)-2-(N-methylanilino)hepta-2,5-dienenitrile 
• 61859-43-6 (2E,4E)-N-methyl-N-phenyl-2,4-hexadienamide 
• 145968-84-9 (2Z,4E)-6-hydroxy-2-(N-methylanilino)hepta-2,4-dienenitrile 
• 145997-77-9 (2E,4E)-6-hydroxy-2-(N-methylanilino)hepta-2,4-dienenitrile 
• 117873-00-4 (2E,4E)-2-(Methyl-phenyl-amino)-hepta-2,4-dienenitrile 
• 117872-99-8 (2E,4E)-2-(Methyl-phenyl-amino)-hepta-2,4-dienenitrile 
• 145968-54-3 (3E,5E)-2-(N-methylanilino)<2-2H>hepta-3,5-dienenitrile 
• 145968-58-7 (2Z,5E)-4-ethyl-2-(N-methylanilino)hepta-2,5-dienenitrile 
• 145968-57-6 (2E,5E)-4-ethyl-2-(N-methylanilino)hepta-2,5-dienenitrile 
• 145997-74-6 (2Z,5E)-4-(3-bromopropyl)-2-(N-methylanilino)hepta-2,5-dienenitrile 
• 145968-71-4 (2E,5E)-4-(3-bromopropyl)-2-(N-methylanilino)hepta-2,5-dienenitrile 

Relevant academic research and scientific papers

Electrophilic Reactions of α-Amino Dienenitriles: Regiochemistry and Stereoselectivity of Trisubstituted Pentadienyl Anions

A pentadienyl anion 7a generated from 2-N-methylanilinohepta-3,5-dienenitrile reacted at the γ-site with halogenoalkanes to give predominantly the products 9γ-22γ having the 2Z,5E-configuration, while it reacted at the ε-site with conjugated aldehydes to

Use of α-Anilino Dienenitriles as Nucleophiles in Cycloadditions

The α-anilino dienenitriles 1-5 were prepared.The dienes 1-3 reacted with dichlorocarbene and electrophiles containing electron-deficient double bonds such as maleic anhydride, benzoquinone, dimethyl acetylenedicarboxylate, tetracyanoethylene, and chlorosulphonyl isocyanate.The diarylmethylamines 8-10, generated by cycloaddition of α-anilino dienenitriles and maleic anhydride, were successfully transformed into acridones 15-17.Intramolecular cyclization of trienes 4 and 5 yielded the carbazoles and dihydro derivatives, accompanied by formation of 2-cyano-1-methylindole.