1459697-08-5Relevant academic research and scientific papers
Efficient synthesis of trifluoromethylated cyclopentadienes/fulvenes/ norbornenes from divinyl ketones
Liu, Xiao,Xu, Xianxiu,Pan, Ling,Zhang, Qian,Liu, Qun
, p. 6703 - 6706 (2013/10/01)
The synthetic methods of trifluoromethylated cyclopentadienes/fulvenes/ norbornenes have been developed using 3-CF3-1,4-dien-3-ols as the synthons, which can be easily prepared by the regiospecific 1,2-addition of the Ruppert-Prakash reagent (TMSCF3) to divinyl ketones. All the reactions are carried out under mild, metal-free conditions to afford the corresponding products in high to excellent yields.
