146028-83-3

Basic information

• Product Name: Silane, [2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethoxy](1,1-dimethylethyl)diphen yl-
• CAS NO: 146028-83-3
• Molecular Formula: C23H32O3Si
• Molecular Weight: 384.591
• Mol File: 146028-83-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, [2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethoxy](1,1-dimethylethyl)diphen yl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethoxy](1,1-dimethylethyl)diphen yl-(146028-83-3)
• EPA Substance Registry System: Silane, [2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethoxy](1,1-dimethylethyl)diphen yl-(146028-83-3)

Safety Data

• Hazardous Substances Data: 146028-83-3(Hazardous Substances Data)

Upstream product

• 32233-43-5 2-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethanol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 120341-92-6 tert-Butyl-(2-{(2S,4S)-4-[(2S,4S)-4-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-1,5-dioxa-spiro[5.5]undec-2-ylmethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-ethoxy)-diphenyl-silane 
• 120341-89-1 (S)-1-{(2R,4S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-3-[2-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-[1,3]dithian-2-yl]-propan-2-ol 
• 120341-90-4 (S)-5-{(2R,4S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-hydroxy-pentan-2-one 
• 120341-91-5 (2R,4S)-1-{(2R,4S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pentane-2,4-diol 
• 120341-93-7 (2S,4S,6S,8S,10S)-12-(tert-Butyl-diphenyl-silanyloxy)-dodecane-1,2,4,6,8,10-hexaol 
• 120341-85-7 (2S,4S,6S)-8-(tert-Butyl-diphenyl-silanyloxy)-octane-1,2,4,6-tetraol 
• 131522-39-9 Toluene-4-sulfonic acid (S)-3-{(2R,4S)-4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-2-hydroxy-propyl ester 
• 120341-86-8 (2S,4S,6S)-8-(O-tert-butyldiphenylsilyl)-4,6-(O-cyclohexylidene)-1,2-(O-isopropylidene)octane-1,2,4,6,8-pentol 
• 120341-82-4 (2S,6S)-8-(O-tert-butyldiphenylsilyl)-1,2-(O-isopropylidene)-4-(trimethylenedithio)octane-1,2,6,8-tetrol 
• 120341-87-9 (S)-3-{(2R,4S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-propane-1,2-diol 
• 120341-88-0 (2S,4S,6S)-8-(O-tert-butyldiphenylsilyl)-4,6-(O-cyclohexylidene)-1,2-epoxyoctane-4,6,8-triol 
• 120341-83-5 (2S,6S)-8-(O-tert-butyldiphenylsilyl)-1,2-(O-isopropylidene)-octan-4-one-1,2,6,8-tetrol 
• 120341-84-6 (2S,4S,6S)-8-(O-tert-butyldiphenylsilyl)-1,2-(O-isopropylidene)-octane-1,2,4,6,8-pentol 
• 133218-78-7 (3S,5S)-1-O-tert-butyldiphenylsilyl-3-O-methanesulfonyl-5-benzenesulfonyl-6-(trimethylsilyl)hexane-1,3-diol 

Relevant articles and documents

A CONVERGENT GENERAL SYNTHETIC PROTOCOL FOR SYN-1,3-POLYOLS

A method for the stereoselective synthesis of syn-1,3-polyols using a chiral building block 1 is described.High syn-stereoselectivity in the reduction of β-hydroxy ketones was achieved using lithium aluminum hydride-lithium iodide.

A stereoselective synthesis of verbalactone-determination of absolute stereochemistry

A total synthesis of verbalactone has been achieved starting from l-malic acid. A total synthesis of verbalactone has been achieved starting from l-malic acid. The two appropriately protected acid and alcohol segments were prepared from l-malic acid and l

Diastereoselective synthesis of 2,5-disubstituted 3-hydroxypyrrolidine and 2,6-disubstituted 3-hydroxypiperidine derivatives by radical cyclisation; synthesis of (+)-bulgecinine and (-)-desoxoprosopinine

Cyclisation of the O-stannyl ketyl, generated from the aldehyde 17 by reaction with tributyltin hydride in the presence of AIBN, gives the 5-benzyloxymethyl-7-hydroxypyrrolooxazolidin-2-ones as a diastereoisomeric mixture of 7α-ol 18 and 7β-ol 19 (2:1), with high diastereoselectivity with respect to the 5,7a positions. (+)-Bulgecinine 8 is enantioselectively synthesised by stereospecific reduction of the ketone 20, derived from compounds 18 and 19. In a similar way, cyclisation of compound 40 gives a 2:1 mixture of compounds 41 and 42. Conversion of compound 41 into (-)-desoxoprosopinine 9 is successfully achieved.