1461649-10-4Relevant academic research and scientific papers
Enantioselective Synthesis of Functionalized Arenes by Nickel-Catalyzed Site-Selective Hydroarylation of 1,3-Dienes with Aryl Boronates
Marcum, Justin S.,Meek, Simon J.,Taylor, Tiffany R.
supporting information, p. 14070 - 14075 (2020/06/10)
A catalytic method for the site-selective and enantioselective synthesis of functionalized arenes by the intermolecular hydroarylation of terminal and internal 1,3-dienes with aryl pinacolato boronates is reported. The reactions are promoted by 5.0 mol %
Transmetal-Catalyzed Enantioselective Cross-Coupling Reaction of Racemic Secondary Benzylic Bromides with Organoaluminum Reagents
Fang, Hong,Yang, Zhiyong,Zhang, Lijun,Wang, Wei,Li, Yimei,Xu, Xiaolong,Zhou, Shuangliu
supporting information, p. 6022 - 6025 (2016/12/09)
The transmetal-catalyzed enantioselective cross-coupling reaction of secondary benzylic electrophiles with organoaluminum reagents has been developed. The reaction of secondary benzylic electrophiles with alkynylaluminum reagents provides a mild way for the chiral propargyl compounds bearing aromatic group in high yields with good enantioselectivities using NiBr2·diglyme and (R)-iPr-Pybox as the catalytic system. The reaction of secondary benzylic electrophiles with alkenylaluminum reagents affords the corresponding chiral aryl alkenes in moderate yields with excellent stereoselectivities using commercially available PdCl2 and (R)-BINAP as the catalytic system.
Pd-Catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids
Ye, Jiang,Zhao, Jingming,Xu, Jing,Mao, Yuxue,Zhang, Yong Jian
, p. 9761 - 9763 (2013/10/21)
An efficient method for Pd-catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids has been described. The reactions proceeded smoothly in the presence of Pd2(dba)3· CHCl3 and racemic BINAP
