146236-96-6Relevant articles and documents
Enantioselective syntheses of polyhydroxylated nortropane derivatives: Total synthesis of (+) and (-)-calystegine B2
Boyer, Francois-Didier,Lallemand, Jean-Yves
, p. 10443 - 10458 (2007/10/02)
(+) and (-)-Calystegine B2 were prepared from D-Glucose via Ferrier reaction followed by regiospecific ring enlargement of a polysubstituted cyclohexanone and intramolecular cyclisation of 4-aminocycloheptanone.
Polyhydroxylated nortropanes starting from D-glucose: Synthesis of homochiral (+) and ( -)-Calystegines B2
Duclos,Mondange,Dureault,Depezay
, p. 8061 - 8064 (2007/10/02)
The cycloheptano-isoxazoline 1, prepared from D-glucose, is converted to 6,7-dideoxy cycloheptitols which are suitable precursors for the synthesis of enantiomerically pure (+) and (-)-Calystegines B2.