Cas 146265-69-2,{PtCl((C6H5)2PCH2CH2P(C6H5)2)(OC(CH3)CH(As(C6H5)3))}(1+)*BF4(1-)={PtCl((C6H5)2PCH2CH2P(C6H5)2)(OC(CH3)CH(As(C6H5)3))}BF4

146265-69-2

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Basic information

Product Name: {PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}⁽¹⁺⁾*BF₄^(1-)={PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}BF₄
Synonyms:
CAS NO:146265-69-2
Molecular Formula:
Molecular Weight: 1078.06
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: {PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}⁽¹⁺⁾*BF₄^(1-)={PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}BF₄(CAS DataBase Reference)
NIST Chemistry Reference: {PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}⁽¹⁺⁾*BF₄^(1-)={PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}BF₄(146265-69-2)
EPA Substance Registry System: {PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}⁽¹⁺⁾*BF₄^(1-)={PtCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OC(CH₃)CH(As(C₆H₅)3))}BF₄(146265-69-2)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 146265-69-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 146265-69-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,6,2,6 and 5 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 146265-69:
(8*1)+(7*4)+(6*6)+(5*2)+(4*6)+(3*5)+(2*6)+(1*9)=142
142 % 10 = 2
So 146265-69-2 is a valid CAS Registry Number.

146265-69-2Upstream product

24143-92-8 acetylmethylidene(triphenyl)-λ⁵-arsane

146265-69-2Downstream Products

146265-69-2Relevant academic research and scientific papers

Synthesis of O-Co-ordinated Platinum(II) Complexes of Carbonyl-stabilized Arsonium Ylides and the Mechanism of Conversion to their C-Co-ordinated Isomers

Facchin, Giacomo,Zanotto, Livio,Bertani, Roberta,Canovese, Luciano,Uguagliati, Paolo

, p. 2871 - 2874 (1993)

The reaction of 2>2 with ylides Ph3AsCHCOR (R = Me, Ph or OMe) led to novel platinum(II) complexes >BF4 (R = Me 1, Ph 2 or OMe 3) in which the carbonyl stabilized arsonium ylides are coordinated to the metal centre via the oxygen carbonyl atom.These derivatives are not stable in chlorinated solvents and slowly undergo isomerization to their C-co-ordinated analogues 4-6 following a first-order rate law.The mechanism proposed for this rearrangement implies both intramolecular and free-ylide promoted intermolecular paths with kobs values of the whole process depending on the basicity of the ylide.

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