14627-75-9Relevant academic research and scientific papers
Addition reactions of nitryl chloride at multiple bonds
Zyk,Bondarenko,Nesterov,Zefirov
, p. 980 - 986 (2007/10/03)
Published data on additio of nitryl chloride to alkenes and possible reaction mechanisms were analyzed. Reactions of nitryl chloride with alkenes differing in the ionization potentials of the double bond and in the abilities to undergo various structural rearrangements were studied. Nitryl chloride was shown to be very sensitive both to the substrate and to the reaction conditions.
A Structurally Characterized Dichloro-manganese(IV) Complex Capable of Halogenating Alkenes
Law, Neil A.,Machonkin, Timothy E.,McGorman, Joel P.,Larson, Erlund J.,Kampf, Jeff W.,Pecoraro, Vincent L.
, p. 2015 - 2016 (2007/10/02)
MnIV(salpn)Cl2 regioselectively trans-halogenates alkenes in a reaction for which the Mn-containing product is also identified; this is the first Mn-based halogenating system for which the reactive and final Mn-containing products are structurally characterized.
Oxidation of thioethers by manganese(IV) oxide-trimethylchlorosilane
Bellesia,Ghelfi,Pagnoni,Pinetti
, p. 1759 - 1769 (2007/10/02)
Thioethers are transformed by manganese(IV) oxide-trimethylchlorosilane in CH3OH in high yields to sulphoxides, exclusively.
Acetal Chlorination with MnO2-Trimethylchlorosilane
Bellesia, Franco,Boni, Monica,Ghelfi, Franco,Grandi, Romano,Pagnoni, Ugo M.,Pinetti, Adriano
, p. 4579 - 4586 (2007/10/02)
α-Chloroacetals are obtained in almost quantitative yields, by treating acetals with MnO2-trimethylchlorosilane in CH3OH:CH3CN (1:1).The halogenation is explained by a ligand-transfer process on an enolether intermediate, mediated by a Mn(IV)-chloride species.Key Words: Acetals, Aldehydes, Chlorination, Maganese(IV)oxide, Trimethylchlorosilane, Ligand-transfer
CHLORINATION OF ALKENES BY MANGANESE(III) CHLORIDE SPECIES
Donnelly, K. D.,Fristad, W. E.,Gellerman, B. J.,Peterson, J. R.,Selle, B. J.
, p. 607 - 610 (2007/10/02)
Several manganese(III) chloride species have been prepared in situ and used as effective chlorinating agents of alkenes.
ROLE OF THE POLYMER BACKBONE ON THE REACTIVITY OF POLYMER-SUPPORTED (DICHLOROIODO)BENZENE
Sket, Boris,Zupan, Marko,Zupet, Pavle
, p. 1603 - 1606 (2007/10/02)
Chlorination of iodinated crosslinked polystyrene with Cl2 gave polyaryliododichloride containing 1.1 mmol of active chlorine per gram of resin, while fluorination of the same iodinated resin with XeF2 gave polyaryliododifluoride, co
Mechanism of Initiation of the Ring-opening Polymerization and Addition Oligomerization of Norbornene Using Unicomponent Metathesis Catalysts
Laverty, D. Theodore,Rooney, John J.
, p. 869 - 878 (2007/10/02)
The identities and yields of the low-molecular-weight products formed during ring-opening polymerization of norbornene in benzene solvent using several unicomponent metal halide catalysts (W, Mo, Re, Ru, Os and Ir) were extensively investigated.Dimers and
