146307-66-6

Basic information

• Product Name: t-butyl 2-<(4-tosyloxy-1-methylbutyl)oxy>propionate
• CAS NO: 146307-66-6
• Molecular Weight: 386.51
• Mol File: 146307-66-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-butyl 2-<(4-tosyloxy-1-methylbutyl)oxy>propionate(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl 2-<(4-tosyloxy-1-methylbutyl)oxy>propionate(146307-66-6)
• EPA Substance Registry System: t-butyl 2-<(4-tosyloxy-1-methylbutyl)oxy>propionate(146307-66-6)

Safety Data

• Hazardous Substances Data: 146307-66-6(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 87044-47-1 cis-2,6-dimethyl-2-hydroxymethyltetrahydropyran 
• 87044-47-1 trans-2,6-dimethyl-2-hydroxymethyltetrahydropyran 

Relevant articles and documents

Diastereoselective Construction of 2,2,6-Trisubstituted Tetrahydropyrans by Intramolecular Alkylation Reaction of Lithiium Enolates Generated from α-Alkoxy Carboxylates

The intramolecular alkylation reaction of enolates of t-butyl α-alkoxy carboxylates in THF-HMPA proceeded stereoselectively to afford 2,2,6-trisubstituted tetrahydropyrans with high cis-selectivity.