14633-13-7

Upstream product

• 14252-32-5 1-phenyl-hex-1-yn-3-one 
• 7803-49-8 hydroxylamine 
• 28164-31-0 C₁₂H₁₃NO 
• 98-59-9 p-toluenesulfonyl chloride 
• 936924-52-6 C₁₉H₁₉NO₃S 
• 110-69-0 butyraldehyde oxime 
• 536-74-3 phenylacetylene 

Relevant academic research and scientific papers

Rhodium(II)-Catalyzed Formal [3 + 2] Cycloaddition of N-Sulfonyl-1,2,3-triazoles with Isoxazoles: Entry to Polysubstituted 3-Aminopyrroles

A novel rhodium(II)-catalyzed formal [3 + 2] cycloaddition of N-sulfonyl-1,2,3-triazoles with isoxazoles has been achieved that provides an efficient method for the synthesis of polysubstituted 3-aminopyrrole derivatives. An operationally simple one-pot synthesis of the titled compounds from terminal alkynes, tosyl azide, and isoxazoles was also developed. The presented reaction affords an illustrative example of employing 1,2,3-triazoles as the [2C]-component in relevant cycloaddition reactions.

Synthesis of isoxazoles by hypervalent iodine-induced cycloaddition of nitrile oxides to alkynes

Treatment of oximes with hypervalent iodine leads to substituted isoxazoles via rapid formation of nitrile oxides. Reaction with terminal alkynes led to a series of 3,5-disubstituted isoxazoles with complete regioselectivity and high yield, in a procedure

Synthesis of isochalcogenazole rings by treating β-(N,N- dimethylcarbamoylchalcogenenyl)alkenyl ketones with hydroxylamine-O-sulfonic acid

β-(N,N-Dimethylcarbamoylselenenyl)- and β-(N,N- dimethylcarbamoyltellurenyl)alkenyl ketones were converted into isoselenazoles and isotellurazole Te-oxides, respectively, simply by treating with hydroxylamine-O-sulfonic acid, and deoxygenation of the latt

Regiospecific Synthesis of Isoxazoles by the Reaction of α-Bromoenones with Hydroxylamine

In the reaction of α-bromoenones with hydroxylamine, the synthesis of isomeric isoxazoles could be controlled regiospecifically by changing the base.