146397-42-4

Basic information

• Product Name: (2S,4R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-4-methyl-cyclohexanone
• CAS NO: 146397-42-4
• Molecular Weight: 408.656
• Mol File: 146397-42-4.mol

Chemical Properties

• CAS DataBase Reference: (2S,4R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-4-methyl-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-4-methyl-cyclohexanone(146397-42-4)
• EPA Substance Registry System: (2S,4R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-4-methyl-cyclohexanone(146397-42-4)

Safety Data

• Hazardous Substances Data: 146397-42-4(Hazardous Substances Data)

Upstream product

• 146397-39-9 (2R,3R,4R)-1,2-Bis-benzyloxy-4-((R)-5-methyl-cyclohex-1-enyl)-pentan-3-ol 
• 91633-77-1 (Z,R)-(3-methylcyclohexane)ethylidene 
• 146397-41-3 (2R,3R,4R)-4-((2R,5R)-2-Hydroxy-5-methyl-cyclohexyl)-pentane-1,2,3-triol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 146397-44-6 (4S,7R)-8-(tert-Butyl-diphenyl-silanyloxy)-4,7-dimethyl-octan-1-ol 
• 146397-43-5 (5R,7S)-7-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-5-methyl-oxepan-2-one 

Relevant articles and documents

Versatile synthesis of alicyclic and acyclic compounds with alternate and remote C-methyl substitution patterns via asymmetric sequential olefination and ene reactions

Treatment of enantiomerically pure alkyl cyclohexane ethylidene derivatives with 2,3-di-O-benzyl D- and L-glyceraldehyde and related aldehydes in the presence of Lewis acids leads to enantiomerically pure or enriched branched alkylcyclohexenes. These can