146444-29-3

Upstream product

• 95530-78-2 7-oxabicyclo[2.2.1]hept-5-en-2-one 
• 111196-99-7 5,5-dimethoxy-7-oxabicyclo[2.2.1]hept-2-ene 
• 5707-04-0 Phenylselenyl chloride 

Downstream Products

• 173243-07-7 (+)-(1R,2S,3S,6S)-2-hydroxy-6-methoxy-4-oxo-3-<(2',3',4',6'-tetra-O-acetyl-α-D-galactopyranosyl)methyl>cyclohexyl acetate 
• 168921-98-0 (+)-(1S,2R,3R,6R)-2-hydroxy-6-methoxy-4-oxo-3-<(2',3',4',6'-tetra-O-acetyl-α-D-galactopyranosyl)methyl>cyclohexyl acetate 

Relevant academic research and scientific papers

Photoreductive cleavage of Phenyl-Selenium Bonds of Phenylselenoalkanes.

Photo-induced-electron transfer from triethylamine to phenylselenoalkanes can lead to selective reduction and cleavage of the Ph-Se bond leading to the formation of benzene and the corresponding alkylselenyl radicals that dimerize.

SUBSTITUENT EFFECTS ON THE REGIOSELECTIVITY OF THE BAEYER-VILLIGER OXIDATION OF 7-OXABICYCLOHEPTAN-2-ONES

New 3-oxysubstituted and 3,6-dioxydisubstituted 7-oxabicycloheptan-2-ones have been prepared.The regioselectivity of their Baeyer-Villiger oxidation has been determined and compared with that of other 7-oxabicycloheptan-2-one derivatives.If