1464894-36-7Relevant academic research and scientific papers
Silver-catalysed intramolecular hydroamination of alkynes with trichloroacetimidates
Wong, Valerie H. L.,Hor, T. S. Andy,Hii, King Kuok
, p. 9272 - 9274 (2013)
Silver(i) complexes catalyse the intramolecular addition of trichloroacetimidates to alkynes. In the absence of a ligand, the selectivity of the reaction is dependent upon the nature of the counter-anion and solvent. The introduction of non-chelating nitrogeneous ligands suppresses competitive Bronsted acid catalysis, improving the yield and selectivity of the reaction.
