146499-16-3

Upstream product

• 23423-65-6 N-(2-Bromophenyl)-2-methylpropenamide 
• 106-95-6 allyl bromide 
• 615-36-1 2-bromoaniline 

Relevant academic research and scientific papers

Intramolecular organolithium addition to indol-2(3H)-ones; an approach to the synthesis of pyrrolo[1,2-a]indoles and pyrido[1,2-a]indoles

Cyclisation of 3 and 10 by lithium-halogen exchange followed by reduction with lithium aluminium hydride gives pyrrolo[1,2-a]indoles 11 and 13 respectively. Similar treatment of bromides 4a and 4b gives pyrido[1,2-a]indoles 12a and 12b. The Royal Society

Aryl Radical Cyclisations involving an Amide Group in the Linking Chain

Cyclisation of 7, 8 and 9 via their derived aryl radicals gives products arising from addition of the aryl radical to the acryloyl double bond exclusively.