146508-35-2

Basic information

• Product Name: 2-triphenylstannyloxy-3,6-di-tert-butyl-1,4-benzoquinone
• CAS NO: 146508-35-2
• Molecular Weight: 585.33
• Mol File: 146508-35-2.mol

Chemical Properties

• CAS DataBase Reference: 2-triphenylstannyloxy-3,6-di-tert-butyl-1,4-benzoquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-triphenylstannyloxy-3,6-di-tert-butyl-1,4-benzoquinone(146508-35-2)
• EPA Substance Registry System: 2-triphenylstannyloxy-3,6-di-tert-butyl-1,4-benzoquinone(146508-35-2)

Safety Data

• Hazardous Substances Data: 146508-35-2(Hazardous Substances Data)

Upstream product

• 23803-85-2 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone 
• 962-89-0 triphenyltin bromide 

Downstream Products

• 152729-24-3 ((CH₃)3C)CCO(Sn(C₆H₅)3)CHC(CH₃)3CCOCOMn(CO)4 
• 152730-54-6 ((CH₃)3C)CCO(Sn(C₆H₅)3)CHC(CH₃)3CCOCOSn(C₆H₅)3 

Relevant articles and documents

SYNTHESIS, STRUCTURE , AND PROPERTIES OF 2-(TRIPHENYLSTANNYLOXY)-3,6-DI-tert BUTYL-1,4-BENZOQUINONE

2-(Triphenylstannyloxy)-3,6-di-tert-butyl-1,4-benzoquinone (1) was obtained from the potassium salt of 3,6-di-tert-butyl-2-hydroxy-1,4-benzoquinone and triphenyltin bromide in methanol and characterized by x-ray diffraction analysis, electronic, IR, and NMR spectroscopy.According to x-ray diffraction data, the single crystal of 1 has the structure of a chain metal polymer with bridging hydroxy-para-quinone ligands; the coordination number of tin is six.Complex 1 is reduced by cobaltocene to the corresponding radical anion.In solutions, 1 reacts with metal-centered radicals SnPh3, PbPh3, and Mn(CO)5 with formation of paramagnetic binuclear ortho-semiquinone complexes. Keywords: 2-triphenylstannyloxy-3,6-di-tert-butyl-1,4-benzoquinone, synthesis, x-ray diffraction analysis, electronic absorption spectra, IR spectroscopy, NMR spectroscopy, reaction with radicals.