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prop-2-en-1-yl diphenylphosphinite is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

14655-53-9

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14655-53-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 14655-53-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,6,5 and 5 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 14655-53:
(7*1)+(6*4)+(5*6)+(4*5)+(3*5)+(2*5)+(1*3)=109
109 % 10 = 9
So 14655-53-9 is a valid CAS Registry Number.

14655-53-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name diphenyl(prop-2-enoxy)phosphane

1.2 Other means of identification

Product number -
Other names Diphenyl-phosphinigsaeure-allylester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14655-53-9 SDS

14655-53-9Relevant academic research and scientific papers

A New Method for Stereoselective Homoallylic Amine Synthesis

Armstrong, Susan K.,Collington, Eric W.,Knight, Julian G.,Naylor, Alan,Warren, Stuart

, p. 1433 - 1448 (2007/10/02)

Nitrile oxide cycloadditions to readily available allylic diphenylphosphine oxides 2 proceeded regioselectively and stereoselectively to give 5-(1'-diphenylphosphinoylalkyl)isoxazolines 4 and 5.These heterocycles were reduced to δ-amino-β-hydroxyalkyldiphenylphosphine oxides 6 and 7 using a combination of sodium borohydride and nickel(II) chloride.Stereospecific elimination of diphenylphosphinic acid from the reduction products using sodium hydride in N,N-dimethylformamide gave homoallylic primary amines 8 and 9 of defined stereochemistry.

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