146558-41-0Relevant academic research and scientific papers
Direct oxidative coupling of arenes with olefins by Rh-catalyzed C-H activation in air: Observation of a strong cooperation of the acid
Zheng, Lu,Wang, Jianhui
supporting information; experimental part, p. 9699 - 9704 (2012/09/21)
A [{RhCl(cod)}2]/CCl3COOH system was developed for the oxidative coupling of non-chelate-assisted arenes with olefins in the presence of catalytic amounts of Cu(OAc)2·H2O as a co-oxidant and oxygen as the terminal oxidant. The acid was an indispensable component in this system and played a very important role in the coupling reaction. This catalytic system was applied to the direct oxidative coupling of a series of arenes and olefins and the corresponding products were afforded in high yields with special chemo- and regioselectivity. This reaction provides an atom-efficient route to vinylarenes, which are widely used in various fine chemicals. Give it some air: A [{RhCl(cod)}2]/CCl3COOH system for the oxidative coupling of arenes and olefins afforded their corresponding products with special chemo- and regioselectivity in high yields. This reaction provides an atom-efficient route to vinylarenes. Copyright
Substituent effects on the solvolysis rates and gas phase stabilities of 1,2,2-trimethyl-1-phenylpropyl and 1,2,2-trimethyl-1-(2-methylphenyl)propyl systems
Nakata, Kazuhide,Fujio, Mizue,Mishima, Masaaki,Nomura, Hideyuki,Tsuno, Yuho,Nishimoto, Kichisuke
, p. 581 - 590 (2007/10/03)
Substituent effects on the solvolysis rates of 1,2,2-trimethyl-1- phenylpropyl chlorides in 80% (v/v) aq acetone at 45 °C and 1,2,2-trimethyl- 1-(2-methylphenyl)propyl p-nitrobenzoates in 50% (v/v) aq ethanol at 75 °C were correlated with the Yukawa-Tsuno
