146566-79-2

Upstream product

• 106357-20-4 (R,R)-diisopropyl tartrate (Z)-crotylboronate 

Downstream Products

• 120040-87-1 methyl 2β-<(E)-1-methyl-3-<(tert-butyldimethylsilyl)oxy>-prop-1-enyl>-5α-(benzyloxy)-7α-hydroxy-1α,6α,8β-trimethyl-1,2,4aα,5,6,7,8,8aβ-octahydronaphthalene-1β-carboxylate 
• 120040-88-2 methyl 2β-<(E)-1-methyl-3-<(tert-butyldimethylsilyl)oxy>-prop-1-enyl>-5α-(benzyloxy)-1α,6α,8β-trimethyl-1,2,4aα,5,6,7,8,8aβ-octahydronaphthalene-1β-carboxylate 
• 120040-84-8 methyl (E,Z,E,E)-(4S,5R,6S,7S)-5-acetoxy-7-(benzyloxy)-9-bromo-14-hydroxy-2,4,6,12-tetramethyltetradeca-2,8,10,12-tetraenoate 
• 120040-85-9 methyl 2β-<(E)-3-hydroxy-1-methylprop-1-enyl>-7α-acetoxy-5α-(benzyloxy)-4-bromo-1α,6α,8β-trimethyl-1,2,4aα,5,6,7,8,8aβ-octahydronaphthalene-1β-carboxylate 
• 120040-80-4 (E)-(4R,5S,6S,7S)-5-Acetoxy-7-benzyloxy-7-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,4,6-trimethyl-hept-2-enoic acid methyl ester 
• 120040-82-6 methyl (E)-(4S,5R,6S,7S)-5-acetoxy-7-(benzyloxy)-9,9-dibromo-2,4,6-trimethylnona-2,8-dienoate 
• 120040-86-0 (1S,2S,5R,6S,7S,8R,8aR)-5-Benzyloxy-7-hydroxy-2-((E)-3-hydroxy-1-methyl-propenyl)-1,6,8-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 146517-98-8 (E)-(4R,5S,6S,7S)-5-Acetoxy-7-benzyloxy-8,9-dihydroxy-2,4,6-trimethyl-non-2-enoic acid methyl ester 
• 120040-79-1 (E)-(4R,5S,6S,7S)-7-Benzyloxy-7-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-2,4,6-trimethyl-hept-2-enoic acid methyl ester 

Relevant academic research and scientific papers

A HIGHLY STEREOSELECTIVE SYNTHESIS OF THE OCTAHYDRONAPHTHALENE SUBUNIT OF KIJANOLIDE AND TETRONOLIDE

A highly stereoselective synthesis of the octahydronaphtalene subunit 4 of kijanolide and tetronolide featuring the intramolecular Diels-Alder reaction of tetraenoate 5 is described.