146606-27-1

Basic information

• Product Name: 1-(1,3-cyclohexadienyl)-propan-2-yl
• Synonyms: 1-(1,3-cyclohexadienyl)-propan-2-yl
• CAS NO: 146606-27-1
• Molecular Weight: 138.21
• Mol File: 146606-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(1,3-cyclohexadienyl)-propan-2-yl(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1,3-cyclohexadienyl)-propan-2-yl(146606-27-1)
• EPA Substance Registry System: 1-(1,3-cyclohexadienyl)-propan-2-yl(146606-27-1)

Safety Data

• Hazardous Substances Data: 146606-27-1(Hazardous Substances Data)

Upstream product

• 146606-25-9 1-<3-(phenylsulfonyl)cyclohexen-3-yl>-propan-2-yl tetrahydropyran-2-yl ether 
• 87413-32-9 (cyclohex-2-enylsulfonyl)benzene 

Downstream Products

• 146606-21-5 1-(1,3-cyclohexadienyl)-propan-2-yl vinylsulfonate 
• 265116-08-3 N-benzyl-N-[1-(1,3-cyclohexadienyl)-propan-2-yl] vinylsulfonamide 
• 265116-12-9 N-benzyl-N-[1-(1,3-cyclohexadienyl)-propan-2-yl]amine 
• 882426-42-8 (1S,3R,6R,8R)-3-Methyl-4-((S)-1-phenyl-ethyl)-5-thia-4-aza-tricyclo[6.2.2.0^1,6]dodec-9-ene 5,5-dioxide 
• 882426-43-9 (1R,3S,6S,8S)-3-Methyl-4-((S)-1-phenyl-ethyl)-5-thia-4-aza-tricyclo[6.2.2.0^1,6]dodec-9-ene 5,5-dioxide 
• 882426-41-7 Ethenesulfonic acid ((S)-2-cyclohexa-1,3-dienyl-1-methyl-ethyl)-((S)-1-phenyl-ethyl)-amide 
• 882426-40-6 Ethenesulfonic acid ((R)-2-cyclohexa-1,3-dienyl-1-methyl-ethyl)-((S)-1-phenyl-ethyl)-amide 
• 882426-39-3 ((S)-2-Cyclohexa-1,3-dienyl-1-methyl-ethyl)-((S)-1-phenyl-ethyl)-amine 
• 882426-38-2 ((R)-2-Cyclohexa-1,3-dienyl-1-methyl-ethyl)-((S)-1-phenyl-ethyl)-amine 
• 265116-11-8 methanesulfonic acid 2-cyclohexa-1,3-dienyl-1-methyl-ethyl ester 

Relevant articles and documents

Intramolecular Diels-Alder Reaction of Vinylsulfonates Derived from Hydroxyalkyl Substituted 1,3-Dienes and Oxidative Desulfurization of the Resultant Sultones

Vinylsulfonates prepared from hydroxyalkyl substituted cycloalka-1,3-dienes and acyclic 1,3-dienes by esterification with vinylsulfonyl chloride cycloadd to δ-sultones at temperatures ranging from 0 deg C to reflux in toluene.High diastereoselectivity is observed for substrates 2 featuring a cyclic 1,3-diene moiety, whereas a substituent R2 larger than hydrogen is necessary to achieve good to excellent levels of stereocontrol for substrates 9 possessing an acyclic 1,3-diene unit.Oxidative desulfurization of the resultant sultones via borylation and subsequent peracid treatment yields hydroxy ketones, thus establishing vinylsulfonyl chloride as a regio- and stereoselectively reacting ketene equivalent for the intramolecular Diels-Alder cycloaddition.