146607-34-3Relevant articles and documents
Reaction of isoquinoline 2-oxides with methylsulfinylmethyl carbanion
Takeuchi,Masuda,Hamada
, p. 2602 - 2604 (1992)
7-Methoxy-3-methylsulfonyl-3H-benz[d]azepine (5) and 2-deuterio-3-(methyl-d3)-sulfonyl-3H-benz[d]azepine (14) were obtained from the reaction of the corresponding isoquinoline 2-oxides with methylsulfinylmethyl carbanion. A revised reaction mechanism is proposed on the basis of the results obtained by use of deuterated dimethyl sulfoxide-d6.