14664-64-3

Upstream product

• 10436-57-4 S-(2-methylphenyl) thioacetate 
• 95-46-5 2-methylphenyl bromide 
• 106-45-6 para-thiocresol 

Downstream Products

• 99586-89-7 (trans-2-chloro-vinyl)-o-tolyl sulfide 
• 57371-82-1 C₁₇H₂₀N₂S 
• 57371-68-3 C₁₆H₁₇ClN₂S 
• 57371-79-6 N'-(4-Bromo-2-methyl-phenyl)-N-methyl-N-o-tolylsulfanyl-formamidine 
• 57371-74-1 N'-(2-Chloro-6-methyl-phenyl)-N-methyl-N-o-tolylsulfanyl-formamidine 

Relevant academic research and scientific papers

A MILD AND CONVENIENT PREPARATION OF SULFENYL CHLORIDES FROM THIOLACETATES

Sulfenyl chlorides are obtained easily and in good yields through the reaction of thiolesters and sulfuryl chloride.

Antidiabetic pyrrolecarboxylic acids

Certain pyrrolecarboxylic and pyrroleacetic acid derivatives substituted on the pyrrole ring with thioether groups, acyl groups, phenyl, substituted phenyl, phenoxy, substituted phenoxy, benzyl or halo and optionally substituted on the pyrrole nitrogen with alkyl, and the pharmaceutically acceptable salts thereof, are useful in lowering the blood glucose levels of hyperglycemic animals.

Antidiabetic furancarboxylic and thiphenecarboxylic acids

Compounds of the structure STR1 wherein Z is oxygen or sulfur; R is (C1 -C2)alkoxy; phenoxy; benzyl; phenylthiomethyl; phenylthio; phenylthio monosubstituted in the 2-, 3- or 4-position with (C1 -C3)alkyl, pheny

Electrophilic additions to allenes. VI. The role of steric versus electronic effects in the reactions of arenesulphenyl halides with allenes

The role of steric and electronic effects during the rate and product determining steps for the addition of arenesulphenyl chlorides to 1,3-disubstituted allenes has been briefly examined.Both effects appear to be generally of minimal importance during the rate determinig step.The available rate data indicate the presence of little, if any, build up of positive charge on sulphur.These results are interpreted in terms of an SN2 attack on bivalent sulphur leading to an alkylidenethiiranium ion intermediate.Steric effects are of greater importance in the product determinig step, particularly when the sulphenyl chlorides possess two bulky ortho substituents, as in the case of 2,4,6-triisopropylbenzenesulphenyl chloride.

N-arylsulfenylated derivatives of benzofuranyl methylcarbamates

A new class of chemical compounds useful for the control of insects consists of (methyl) (arylsulfenyl)-carbamic acid esters of 2,3-dihydro-2,2-dimethyl-7-benzofuranol. The preparation of these compounds, their physical properties, formulation, and use to control both household insects and crop insects are exemplified.