146680-74-2Relevant academic research and scientific papers
INVESTIGATION OF THE STRUCTURES OF AND THE INTRAMOLECULAR INTERACTIONS IN N-VINYLAMIDES BY MEANS OF MULTINUCLEAR NMR SPECTROSCOPIC (1H, 13C, 15N, 17O) DATA AND THE RESULTS OF QUANTUM-CHEMICAL CALCULATIONS
Afonin, A. V.,Trofimov, B. A.,Malysheva, S. F.,Vashchenko, A. V.
, p. 181 - 190 (2007/10/02)
As a result of an analysis of the parameters of the 1H, 13C, 15N, and 17O NMR spectra of a number of N-vinylanilides it was established that the phenyl ring is orthogonal to the plane of the amido group, while the vinyl and carbonyl groups are coplanar.Th
SINGLE-STAGE SYNTHESIS OF 3-ARYLAMINO-1-BUTYNES FROM ANILIDES AND ACETYLENE
Trofimov, B. A.,Malysheva, S. F.,Vyalykh, E. P.
, p. 1405 - 1409 (2007/10/02)
3-Arylamino-1-butynes were obtained with 20-50percent yields by the reaction of anilides and acetylene (130-160 deg C, initial pressure 12 atm) in the presence of the superbasic system formed during the hydrogenolysis of the anilide by metallic potassium in tetrahydrofuran or dioxane.
