146681-69-8

Basic information

• Product Name: 9-Borabicyclo[3.3.1]nonane, 9-[[3,5-bis(trifluoromethyl)benzoyl]oxy]-
• CAS NO: 146681-69-8
• Molecular Formula: C17H17BF6O2
• Molecular Weight: 378.122
• Mol File: 146681-69-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-Borabicyclo[3.3.1]nonane, 9-[[3,5-bis(trifluoromethyl)benzoyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Borabicyclo[3.3.1]nonane, 9-[[3,5-bis(trifluoromethyl)benzoyl]oxy]-(146681-69-8)
• EPA Substance Registry System: 9-Borabicyclo[3.3.1]nonane, 9-[[3,5-bis(trifluoromethyl)benzoyl]oxy]-(146681-69-8)

Safety Data

• Hazardous Substances Data: 146681-69-8(Hazardous Substances Data)

Upstream product

• 725-89-3 3,5-bistrifluoromethylbenzoic acid 
• 21205-91-4 9-borabicyclo[3.3.1]nonane dimer 

Relevant articles and documents

Monomeric and Dimeric Acyloxydialkylboranes

The carboxylic acids RCO2H t a, Et b, 3,4,5-(MeO)3C6H2 c, 4-MeOC6H4 d, Ph e, 2,4,6-Me3C6H2 f, 2,6-Cl2C6H3 g, or 3,5-(CF3)2C6H3 h> were treated with triethylborane or with bis(9-borabicyclononane) to give the acyloxydiethylboranes 1a-1h and the 9-acyloxy-9-(borabicyclononanes) 2a-2h, respectively.Compounds 1a-1h are largely unassociated in nonpolar solvents ((11)B NMR, IR spectroscopy).As pure liquids, or in the solid state, they form equilibrium mixtures of monomeric and associated (dimeric) molecules (IR spectroscopy).Compounds 2a-2f are completely associated as pure liquids and in the solid state, but only weakly associated in non-polar solvents.Based in the crystal structure of dimeric 2e, it is proposed that, when associated, derivatives of both 1 and 2 form cyclic dimers.