146758-98-7Relevant academic research and scientific papers
Copper-Catalyzed Asymmetric Hydroallylation of Vinylsilanes
Guo, Xiaobing,Niu, Junbo,Wang, Simin,Xiong, Tao,Zhang, Qian,Zhang, Qiao
, (2022/02/21)
A copper-catalyzed asymmetric hydroallylation of readily available vinylsilanes with allylic phosphates in the presence of hydrosilane was developed. These transformations can be performed under mild reaction conditions and provide the useful chiral organ
The Regiochemistry and Stereochemistry of the Hydroboration of Allylsilanes
Fleming, Ian,Lawrence, Nicholas J.
, p. 3309 - 3326 (2007/10/02)
The hydroboration of a wide range of allylsilanes 3 and 5-21 is found to be generally regioselective for attachment of the boron to C-3 and hydrogen to C-2 of the allyl unit, and to be generally stereoselective in the sense 1, with attachment of the boron
