146855-75-6Relevant academic research and scientific papers
Cumulated Trienephosphine Oxides. Bimolecular Trapping of an Alkylidenecyclopropylidene
Santelli-Rouvier, Christiane,Toupet, Lo?c,Santelli, Maurice
, p. 9039 - 9047 (2007/10/03)
Dihalocarbene addition to allenic phosphine oxides occurs mainly at the allylic double bond. Treatment of dibromocarbene adducts with BuLi leads to cumulated trienephosphine oxides. In some cases, the intermediate alkylidenecyclopropylidene (or its precur
Cumulated trienephosphine oxides. Trapping of an alkylidenecyclopropylidene
Santelli-Rouvier,Santelli
, p. 7843 - 7844 (2007/10/02)
Treatment by BuLi of dibromocarbene adducts on allenic phosphine oxides leads to alkylidenecyclopropylidene that, in one case, is an exceptional stabilized cyclopropylidene: This carbene is trapped by the corresponding cumulated trienephosphine oxide in a
