14694-40-7Relevant academic research and scientific papers
Photochemical reactions of quinoid compounds with phophorus derivatives
Alberti, Angelo,Hudson, Andrew,Pedulli, Gian Franco,McGimpsey, W. Grant,Wan, Jeffrey K. S.
, p. 917 - 921 (2007/10/02)
The photoreactions of tetraethylpyrophosphite, tetraphenylbiphosphine, diphenylphosphine oxide, and tetraethylbiphosphine disulphide with five quinones or quinonoid compounds have been studied by esr spectroscopy; P(O)Ph2 and P(O)(OEt)2 radicals add to both carbon- carbon and carbon-oxygen double bonds, whilst with Ph2P and P(S)Et2 radicals only the species resulting from addition to a carbonyl group are observed.It is also reported that the photogenerated quinone triplets react with tetraethylpyrophosphite leading to the formation of diethoxyphosphonyl radicals, which in turn add to other ground state quinone molecules, the diethoxyphosphinyl adduct to a carbonyl group being also formed in the process.
