1469445-05-3

Upstream product

• 615-37-2 ortho-methylphenyl iodide 
• 693-02-7 hex-1-yne 
• 100-58-3 phenylmagnesium bromide 
• 321555-10-6 1-(hex-1-yn-1-yl)-2-methylbenzene 

Relevant academic research and scientific papers

Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii)

A simple and efficient catalytic arylmagnesiation of diarylacetylenes and aryl(alkyl)acetylenes is accomplished by NiCl2·6H2O at r.t. in the absence of stabilising ligands. The corresponding tetra-substituted alkenes can be obtained in good yields by subsequent treatment with different electrophiles. The Royal Society of Chemistry 2013.