14695-07-9

Basic information

• Product Name: Mn(CO)3(NO)(P(C₆H₅)3)
• CAS NO: 14695-07-9
• Molecular Weight: 431.266
• Mol File: 14695-07-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mn(CO)3(NO)(P(C₆H₅)3)(CAS DataBase Reference)
• NIST Chemistry Reference: Mn(CO)3(NO)(P(C₆H₅)3)(14695-07-9)
• EPA Substance Registry System: Mn(CO)3(NO)(P(C₆H₅)3)(14695-07-9)

Safety Data

• Hazardous Substances Data: 14695-07-9(Hazardous Substances Data)

Upstream product

• 75008-28-5 (acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Highly reduced organometallics 52. Synthesis and chemistry of tricarbonylnitrosylmanganate(2-), [Mn(CO)3(NO)]2-

Treatment of Mn(CO)3(NO)(PPh3) in THF at 20°C with excess sodium amalgam, followed by treatment with cryptand 2.2.2, or with two equiv. of potassium tri-sec-butylborohydride afforded high isolated yields (≥ 80%) of air sensitive yellow solids identified as [Na(crypt.2.2.2)]2[Mn(CO)3(NO)] and K2[Mn(CO)3(NO)], respectively. These products contain the only known mixed carbonylnitrosylmetallate dianion, isoelectronic with [Fe(CO)4]2- and [Mn(CO)4]3-. Reactions of [Mn(CO)3(NO)]2- with Ph3SnCl, Mn(CO)4(NO) and Fe(CO)5, followed by metathesis, provided the new derivatives [Et4N][Mn(CO)3(NO)(SnPh3)], [PPN]2[Mn2(CO)6(NO)2], and [PPN]2[MnFe(CO)7(NO)]. On the basis of IR spectral data the latter two have been formulated to contain non-bridged structures analogous to that previously established for the isoelectronic salt [PPN]2[Fe2(CO)8]. (C) 2000 Elsevier Science S.A.