146980-53-2

Upstream product

• 146980-56-5 (R)-(E)-1-(Trimethylsilyl)-2-methyl-1-buten-3-yl acetate 
• 147058-74-0 (E)-(R)-3-Methyl-4-trimethylsilanyl-but-3-en-2-ol 
• 147058-73-9 (S)-(E)-1-(Trimethylsilyl)-2-methyl-1-buten-3-ol 
• 146980-55-4 (E)-3-Methyl-4-trimethylsilanyl-but-3-en-2-ol 
• 1026608-84-3 Acetic acid (E)-2-methyl-1-trimethylsilanyl-but-2-enyl ester 
• 146980-54-3 (E)-2-Methyl-1-trimethylsilanyl-but-2-en-1-ol 
• 60656-87-3 benzyloxyacetoaldehyde 
• 497-02-9 (E)-2-methyl-2-buten-1-ol 
• 1027600-45-8 ((2R,3S,4R,5S)-5-Benzyloxymethyl-3,4-dimethyl-3-trimethylsilanyl-tetrahydro-furan-2-yl)-acetic acid methyl ester 
• 146980-50-9 (E)-(3S)-Methyl 4-methyl-3-(trimethylsilyl)hex-4-enoate 

Relevant academic research and scientific papers

Acyclic Diastereoselectivity in the Lewis Acid Promoted Additions of Chiral, β-Methyl-Substituted (E)-Crotylsilanes with Achiral Aldehydes

The diastereoselection in the Lewis acid promoted addition of chiral, β-methyl-substituted (E)-crotylsilanes (S)-1a and (R)-1b with α-(benzyloxy)acetaldehyde (2) is reversed from syn to anti by changing the Lewis acid from BF3*OEt2 (non-chelation-controll