1469991-11-4

Basic information

• Product Name: 4'-methyl-2-phenoxy-1,1-biphenyl
• Synonyms: 4'-methyl-2-phenoxy-1,1-biphenyl
• CAS NO: 1469991-11-4
• Molecular Weight: 260.335
• Mol File: 1469991-11-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4'-methyl-2-phenoxy-1,1-biphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-methyl-2-phenoxy-1,1-biphenyl(1469991-11-4)
• EPA Substance Registry System: 4'-methyl-2-phenoxy-1,1-biphenyl(1469991-11-4)

Safety Data

• Hazardous Substances Data: 1469991-11-4(Hazardous Substances Data)

Upstream product

• 624-31-7 4-tolyl iodide 
• 108238-09-1 2-phenoxyphenylboronic acid 
• 34883-46-0 1-(2-iodophenoxy)benzene 
• 5720-05-8 4-methylphenylboronic acid 

Relevant articles and documents

Intramolecular Aryl Migration of Diaryliodonium Salts: Access to ortho-Iodo Diaryl Ethers

By using vicinal trifluoromethanesulfonate-substituted diaryliodonium salts, a novel approach was developed for the synthesis of ortho-iodo diaryl ethers by intramolecular aryl migration. The reaction conditions are mild with a broad substrate scope. Mechanistic insight suggests a sulfonyl-directed nucleophilic aromatic substitution pathway. Additionally, the product ortho-iodo diaryl ethers serve as versatile synthons as demonstrated with several coupling reactions. Furthermore, a useful thyroxine analogue of the 3-iodo-l-thyronine (3-T1) derivative was synthesized by this aryl migration procedure.