147048-67-7Relevant academic research and scientific papers
The asymmetric dihydroxylation of some alkenyl 2-acetylamino-2-deoxy-β-d-glucopyranosides: The preparation of optically pure epoxides as putative inhibitors of chitinases
Fairweather, Jon K.,Stick, Robert V.,Tilbrook, D. Matthew G.
, p. 471 - 482 (2007/10/03)
Various alkenyl 2-acetylamino-2-deoxy-β-D-glucopyranosides have been subjected to the Sharpless asymmetric dihydroxylation protocol to yield the corresponding diols, albeit with somewhat disappointing stereoselectivity. An alternative, more traditional ap
Asymmetric Induction in the Epoxidation of Alkenyl Glycosides of Tri-O-acetyl-N-acetyl-β-D-glucosamine
Peter, Martin G.,Boldt, Peter-C.,Petersen, Stefan
, p. 1275 - 1280 (2007/10/02)
The reaction of alkenyl glycosides 2a - 2c with MCPBA gives diastereoisomeric mixtures of epoxides 3 and 4.The asymmetric induction decreases in the order 2a >> 2b > 2c.The absolute configuration of epoxyalkyl glycosides is determined by correlation with
