14707-75-6Relevant articles and documents
HETEROADAMANTANES AND THEIR DERIVATIVES. 4. SYNTHESIS OF 1,3,5-TRIAZAADAMANTANE
Kuznetsov, A. I.,Kosmakov, V. A.,Unkovskii, B. V.
, p. 697 - 700 (1985)
Reduction of 7-nitro-1,3,5-triazaadamantane with hydrazine hydrate in the presence of Raney nickel gave 7-hydroxyamino- and 7-amino-1,3,5-triazaadamantane, from which 7-chloro-, 7-bromo-, and 7-thiocyanato-1,3,5-triazaadamantanes were synthesized by substitutive deamination.Desulfurization of 7-thiocyanato-1,3,5-triazaadamantane in the presence of Raney nickel gave 1,3,5-triazaadamantane.
7-(N-Methyl-N-alkylamino)-1,3,5-triazaadamantanes
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, (2008/06/13)
A series of high-density 7-(N-methyl-N-alkylamino)-1,3,5 triazaadamantanesre prepared. The preparation involves first adding the alkyl group to the parent amine by reacting the amine with a suitable aldehyde and hydrogen in the presence of a platinum catalyst and then reacting the thus produced secondary amine with formaldehyde and hydrogen in the presence of a nickel catalyst to produce the final product. The series represents a new class of fuels which is particularly useful in volume-limited applications.