147071-68-9Relevant academic research and scientific papers
C2-symmetric bis-sulfoxides as chiral ligands in metal catalysed asymmetric Diels-Alder reactions
Khiar,Fernandez,Alcudia
, p. 123 - 126 (1993)
(S,S)-bis-p-Tolylsulfinylmethane, 1, and (S,S)-2,2-bis-(p-Tolylsulfinyl)propane, 2, were converted into their Fe(III) complexes I and II, respectively. These complexes were shown to be good chiral catalysts of the Diels-Alder reaction between 3-acryloyl-1
Synthesis of chiral β-disulfoxides and their racemization with strong bases
Asensio, Gregorio,Aleman, Pedro A.,Medio-Simon, Mercedes
, p. 3647 - 3650 (1997)
β-Disulfoxides can be obtained from different α-sulfinylcarbanions and sulfinates. While α-unsubstituted and monosubstituted β-disulfoxides are configurationally stable in the presence of strong bases, α,α-disubstituted β-disulfoxides epimerize through an
Bis-sulfoxides as ligands for platinum complexes
Mallorquin, Rocio Martinez,Chelli, Saloua,Brebion, Franck,Fensterbank, Louis,Goddard, Jean-Philippe,Malacria, Max
scheme or table, p. 1695 - 1700 (2010/10/19)
In this article, we describe two new platinum(II) complexes incorporating C2-symmetric enantiopure bis-sulfoxides ligands. The originality of these structures resides in the one-carbon tether between the two sulfoxide functions. X-ray structure
