147161-72-6Relevant academic research and scientific papers
Iodine catalyzes C-glycosidation of D-glucal with silylacetylene
Saeeng, Rungnapha,Sirion, Uthaiwan,Sahakitpichan, Poolsak,Isobe, Minoru
, p. 6211 - 6215 (2003)
A convenient method for C-glycosidation (alkynylation) with various silylacetylenes to D-glucal by iodine molecule via iodo-oxonium intermediates provided exclusively the α-acetylene glycoside products. Eleven successful examples are shown under this cond
C-Glycosidation with silylacetylenes to D-glucals
Tsukiyama, Takahiro,Isobe, Minoru
, p. 7911 - 7914 (2007/10/02)
C-Glycosidation is of significance for introducing carbon chains to sugar nuclei from the chiral pool. Silylacetylenes have been shown to be sufficiently reactive for the selective introduction of acetylenic groups, usefull for organic synthesis.
