147165-86-4

Upstream product

• 100777-91-1 (2S)-2,3-O-isopropylideneglyceraldehyde N-benzylimine 
• 1730-25-2 allylmagnesium bromide 
• 91190-38-4 N-benzyl-2,3-O-isopropylidene-D-glyceraldehyde nitrone 
• 147165-81-9 *,R^*)>-N-hydroxy-2,2-dimethyl-N-(phenylmethyl)-α-(2-propenyl)-1,3-dioxolane-4-methanamine 

Downstream Products

• 885500-85-6 Benzyl-[(S)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyl]-carbamic acid tert-butyl ester 
• 200499-65-6 (S)-1-benzyloxycarbonyl-2-[(S)-1,2-dihydroxyethyl]pyrrolidine 
• 200499-64-5 (2S,4'S)-N-Benzyloxycarbonyl-2-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)pyrrolidine 
• 147165-87-5 (2S,3S)-1-(tert-butyldiphenylsilyloxy)-3-<(phenylmethyl)amino>-5-hexen-2-ol 
• 90600-20-7 (2S)-2-[(tert-butoxycarbonyl)amino]pent-4-enoic acid 

Relevant academic research and scientific papers

Switch in regioselectivity of epoxide ring-opening by changing the organometallic reagent

The regio- and stereoselective ring-opening of a 2-(2′-oxiranyl)-1,2, 3,6-tetrahydropyridine using organometallic reagents is reported. The choice of the organometallic reagent determines the formation of either 2-[(R)-1-hydroxyalkyl]- or 2-[(S)-2-hydroxy

High stereocontrol in the allylation of chiral non-racemic α-alkoxy and α-amino nitrones

The stereocontrolled addition of allylic metals to chiral non-racemic nitrones promoted by the addition of Lewis acids is described. Whereas for α-alkoxy nitrones the stereocontrol depends on the Lewis acid used as an activator, for α-amino nitrones the d

Iodocyclization of Homoallylic Hydroxylamines Derived from D-Glyceraldehyde

The reaction of allylmagnesium chloride with nitrone 1 derived from D-glyceraldehyde affords two diastereoisomeric homoallylic hydroxylamines 2a and 3a which, after separation and O-silylation, are subjected to iodocyclization using N-iodosuccinimide.The