147198-34-3Relevant academic research and scientific papers
Design of 1,2-dioxines with anti-Candida activity: aromatic substituted 1,2-dioxines
Macreadie, Ian G.,Avery, Thomas D.,Robinson, Tony V.,Macreadie, Peter,Barraclough, Miles,Taylor, Dennis K.,Tiekink, Edward R.T.
, p. 1225 - 1232 (2008/09/17)
In an ongoing effort to rationally design new antimicrobials, 47 new 1,2-dioxines have been synthesised. Broad antifungal structure-activity relationships governing aromatically substituted epoxy-1,2-dioxines 2 and 3 and their parent 1,2-dioxines 1 were a
Electron-transfer Photochemistry of Endoperoxides
Takahashi, Yasutake,Wakamatsu, Kan,Morishima, Shin-ichi,Miyashi, Tsutomu
, p. 243 - 253 (2007/10/02)
Derivatives of 1,2-dioxacyclohex-4-ene and 2,3-dioxabicyclooct-5-ene (endoperoxides, EPs) form EDA complexes with tetracyanoethylene (TCNE).The phenyl-substituted EPs 3a, 4a, 4b and 6 undergo electron-transfer-induced reactions when the EDA complexes are irradiated.Two types of reactions are observed depending on the ring system.Monocyclic EPs (3a, 4a and 4b) afford furan derivatives, possibly through the Criegee-type rearrangement, and dehydration, whereas the bicyclic EP 6 undergoes cycloreversion through the C-O bond cleavage.
