147244-79-9

Upstream product

• 157072-60-1 carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 
• 147138-99-6 (CH₂CH)Sn(C₆H₄CH₃)3 

Downstream Products

• 174686-18-1 Ru(Sn(C₆H₄CH₃)3)(S₂CN(CH₃)2)(CO)(P(C₆H₅)3)2 
• 174686-19-2 Ru(Sn(C₆H₄CH₃)3)(S₂CN(C₂H₅)2)(CO)(P(C₆H₅)3)2 
• 174686-11-4 Ru(Sn(C₆H₄CH₃)3)Cl(CO)2(P(C₆H₅)3)2 
• 147244-81-3 Ru(Sn(C₆H₄CH₃)3)Cl(CO)(P(C₆H₅)3)2(CNC₆H₄CH₃) 

Relevant academic research and scientific papers

Coordinatively unsaturated stannyl complexes of ruthenium(II) via a new synthetic route involving vinylstannanes: Molecular structure of Ru(SnMe3)Cl(CO)(PPh3)2

Treatment of RuHCl(CO)(PPh3)3 (1) with (CH2=CH)SnR3 (R = p-tolyl, Me) affords high yields of the coordinatively unsaturated complexes Ru(SnR3)Cl-(CO)(PPh3)2 (R = p-tolyl (2), Me (3)) probably via insertion of the vinylstannane into the ruthenium hydride bond followed by a β-stannyl elimination from the resulting β-stannylethyl complex. The p-tolyl derivative 2 is unstable with respect to a p-tolyl migration to ruthenium, forming Ru(p-tolyl)Cl(CO)(PPh3)2. The molecular geometry of Ru(SnMe3)Cl(CO)(PPh3)2 (3) has been determined by a single-crystal X-ray diffraction study.