147244-80-2

Upstream product

• 157072-60-1 carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 
• 754-06-3 vinyltrimethyltin 

Downstream Products

• 174686-22-7 Ru(Sn(CH₃)3)(C₆H₅CO₂)(CO)(P(C₆H₅)3)2 
• 174686-16-9 Ru(Sn(CH₃)3)(S₂CN(C₂H₅)2)(CO)(P(C₆H₅)3)2 
• 174686-15-8 Ru(Sn(CH₃)3)(S₂CN(CH₃)2)(CO)(P(C₆H₅)3)2 
• 174686-09-0 Ru(Sn(CH₃)3)Cl(CO)2(P(C₆H₅)3)2 
• 174686-21-6 Ru(Sn(CH₃)3)(CH₃CO₂)(CO)(P(C₆H₅)3)2 
• 174686-20-5 Ru(Sn(CH₃)3)(HCO₂)(CO)(P(C₆H₅)3)2 
• 151781-57-6 Ru(Sn(CH₃)3)(Cl)(CO)(P(C₆H₅)3)2(CNC₆H₄CH₃) 

Relevant academic research and scientific papers

Coordinatively unsaturated stannyl complexes of ruthenium(II) via a new synthetic route involving vinylstannanes: Molecular structure of Ru(SnMe3)Cl(CO)(PPh3)2

Treatment of RuHCl(CO)(PPh3)3 (1) with (CH2=CH)SnR3 (R = p-tolyl, Me) affords high yields of the coordinatively unsaturated complexes Ru(SnR3)Cl-(CO)(PPh3)2 (R = p-tolyl (2), Me (3)) probably via insertion of the vinylstannane into the ruthenium hydride bond followed by a β-stannyl elimination from the resulting β-stannylethyl complex. The p-tolyl derivative 2 is unstable with respect to a p-tolyl migration to ruthenium, forming Ru(p-tolyl)Cl(CO)(PPh3)2. The molecular geometry of Ru(SnMe3)Cl(CO)(PPh3)2 (3) has been determined by a single-crystal X-ray diffraction study.