147247-58-3Relevant academic research and scientific papers
Dual gold catalysis: Synthesis of polycyclic compounds via C-H insertion of gold vinylidenes
Wieteck, Marcel,Tokimizu, Yusuke,Rudolph, Matthias,Rominger, Frank,Ohno, Hiroaki,Fujii, Nobutaka,Hashmi, A. Stephen K.
supporting information, p. 16331 - 16336 (2015/01/09)
New and interesting polycyclic compounds have been synthesized from non-conjugated diyne systems by dual gold catalysis. A quaternary carbon center in the backbone and the accompanying Thorpe-Ingold effect enabled the unprecedented insertion of sp3 and sp2 C-H bonds that for the first time were incorporated within the backbone of the diyne system and allowed the construction of complex polycyclic carbon scaffolds inaccessible by previous approaches in which the C-H bonds for the insertion were situated at the other end of the alkyne.
Novel α-arylnitriles synthesis via Ni-catalyzed cross-coupling of α-bromonitriles with arylboronic acids under mild conditions
Yang, Yingying,Tang, Shan,Liu, Chao,Zhang, Huimin,Sun, Zhexun,Lei, Aiwen
supporting information; experimental part, p. 5343 - 5345 (2011/09/13)
An applicable and easy-handling Ni-catalyst can be used to promote direct arylation of α-bromonitriles with various arylboronic acids to construct α-arylnitriles under mild conditions. The methodology tolerates β-hydrogens and functional groups in the substrates.
