147263-10-3Relevant academic research and scientific papers
Diversion from bicyclo[4.2.0]octanol formation through the use of vinyl electrophiles
Loughlin, Wendy A.,Rowen, Catherine C.,Healy, Peter C.
, p. 2220 - 2226 (2005)
Bicyclo[4.2.0]octanols can be obtained from the reaction of phenyl vinyl sulfoxide and the lithium enolate of cyclohexanone under controlled conditions. Diversion to alkylation or Michael-Michael-ring closure was observed when alternative vinyl electrophi
Ring Expansion by Intramolecular Acylation of Phosphine Oxides
Wallace, Paul,Warren, Stuart
, p. 3169 - 3172 (2007/10/02)
Alkylation of cyclic ketones with 2-Ph2PO-ethyl or 3-Ph2PO-propyl groups followed by Baeyer-Villiger oxidation and acyl transfer gives cyclic hydroxy ketones containing two or three more carbon atoms in the ring.
