147297-69-6Relevant academic research and scientific papers
Synthesis and Highly Diastereoselective Nucleophilic Epoxidation of N-(p-Tolylsulfonyl)vinylsulfoximines
Bailey, Peter L.,Clegg, William,Jackson, Richard F. W.,Meth-Cohn, Otto
, p. 343 - 350 (2007/10/02)
N-(p-Tolylsulfonyl)vinylsulfoximines 3 may be prepared in good yield in a one-pot process by reaction of lithiated S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfoximine with aldehydes, followed by elimination using methanesulfonyl chloride-triethylamine.The vi
Very High Diastereofacial Selectivity in the Nucleophilic Epoxidation of N-(p-Tolylsulphonyl)vinylsulphoximines
Bailey, Peter L.,Clegg, William,Jackson, Richard F. W.,Meth-Cohn, Otto
, p. 200 - 202 (2007/10/02)
Nucleophilic epoxidation of N-(p-tolylsulphonyl)vinylsulphoximines (6) using lithium t-butylhydroperoxide proceeds with very high diastereofacial selectivity, the sense of which was established by a single crystal X-ray structure determination, to give N-
