147298-38-2Relevant academic research and scientific papers
A Total Synthesis of 6,7-Dihydroeponemycin and Determination of Stereochemistry of the Epoxide Ring
Hoshi, Hideaki,Ohnuma, Takeshi,Aburaki, Shimpei,Konishi, Masataka,Oki, Toshikazu
, p. 1047 - 1050 (2007/10/02)
A total synthesis of 6,7-dihydroeponemycin 2 was achieved via the epoxide intermediate 8a.Unresolved absolute configuration of the epoxide ring in 2 and eponemycin 1 was determined to be 2R by application of the asymmetric Sharpless epoxidation of 9.
