147329-43-9Relevant academic research and scientific papers
A one-pot esterification of chiral O-trimethylsilyl-cyanohydrins with retention of stereochemistry
Norsikian, Stephanie,Holmes, Ian,Lagasse, Franz,Kagan, Henri B
, p. 5715 - 5717 (2007/10/03)
Enantiomerically enriched O-TMS cyanohydrins have been transformed directly into O-acyl-cyanohydrins using various anhydrides or acid chlorides in the presence of catalytic amounts of scandium(III) triflate. The reaction occurs with full retention of ster
Method of preparing optically active cyanohydrin derivatives
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, (2008/06/13)
The invention relates to a method of preparing an optically active cyanohydrin carboxylic acid ester from an optically active cyanohydrin of opposite configuration, wherein said starting cyanohydrin is converted with a carboxylic acid in the presence of a
Inversion of the configuration of cyanohydrins by a Mitsunobu esterification reaction
Warmerdam, Erwin G. J. C.,Brussee, Johannes,Kruse, Chris G.,Van Der Gen, Arne
, p. 1063 - 1070 (2007/10/02)
Optically active (R)-cyanohydrins have been transformed into cyanohydrin esters of opposite configuration under Mitsunobu conditions and subsequently solvolyzed to (S)-cyanohydrins in high chemical and optical yield. The method works well for allylic and
Inversion of the Configuration of Cyanohydrins by a Mitsunobu Esterification Reaction
Warmerdam, E. G. J. C.,Brussee, J.,Kruse, C. G.,Gen, A. van der
, p. 3 - 6 (2007/10/02)
Optically active (R)-cyanohydrins have been transformed into cyanohydrin esters of opposite configuration under Mitsunobu conditions and subsequently solvolyzed to (S)-cyanohydrins in high chemical and optical yield. The method works well for allylic and
