147375-89-1Relevant academic research and scientific papers
Acylation-cyclization of allenes
Bates, Roderick W.,Rama-Devi, Thota,Ko, Huei-Huei
, p. 12939 - 12954 (2007/10/02)
Allenes bearing a nucleophilic group cyclize on treatment with acyltetracarbonyl cobalt complexes in the presence of mild bases. Various nucleophilic groups and cobalt complexes can be used to give highly functionalized pyrrolidines, cyclopentanes and tet
Synthesis of Medium Ring Azacycles via Allene-based Cyclizations: Evaluation of Possible Mechanistic Pathways
Davies, Ian W.,Shaw, Robert W.,Wisedale, Richard,Gallagher, Timothy
, p. 3557 - 3562 (2007/10/02)
Two pathways have been evaluated to account for the I2-mediated cyclisation of the allenic sulfonamides 1a-e based on (i) the steric demands of the allenic unit, and (ii) the ambident reactivity of the sulfonamide anion.The 1,3-disubstituted allenic sulfo
