14738-99-9Relevant academic research and scientific papers
METHOD FOR PRODUCING METHYLENE-1,3-DIOXOLANES
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Paragraph 0051; 0052; 0053; 0054; 0060; 0061; 0062; 0063, (2015/01/07)
The present invention relates to a novel method for preparing methylene-1,3-dioxolanes of the general formula (1) in which R1 and R2 have the meanings stated in the description. Methylene-1,3-dioxolanes are important intermediates for preparing pyrazoles and anthranilic acid amides, which may be used as insecticides.
Fragmentation of Cyclic Carboxonium Ions, IV. - Synthesis of β-Oxa-γ, δ-enones
Mattay, Jochen,Thuenker, Walter,Scharf, Hans-Dieter
, p. 1105 - 1117 (2007/10/02)
The proton-catalyzed fragmentation of 4-methylene-1,3-dioxolanes 2 by weak acids (pK > 4.3) or weak acidic ion exchangers leads in good yields to β-oxa-γ, δ-enones 5 which are thus easily and generally available for the first time.
