147385-14-6Relevant academic research and scientific papers
First example of 'diastereotopic face activation' and chiral recognition without metal assistance. A novel 5-deazaflavin enzyme model
Kawamoto,Tomishima,Kunitomo,Yoneda,Hayami
, p. 7173 - 7176 (1992)
A chiral 5-deazaflavin 1 with 2-hydroxynaphthyl group at N(3) position of the pyrimidine ring moiety was synthesized. 1 underwent, in the absence of magnesium ion, a '(net) hydride transfer' from BNAH to C(5) almost exclusively on the face where OH group
