1474011-52-3

Basic information

• Product Name: (4,4'-(di-tert-butyl)-2,2'-bipyridine)Ni^III₂
• CAS NO: 1474011-52-3
• Molecular Weight: 580.901
• Mol File: 1474011-52-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4,4'-(di-tert-butyl)-2,2'-bipyridine)Ni^III₂(CAS DataBase Reference)
• NIST Chemistry Reference: (4,4'-(di-tert-butyl)-2,2'-bipyridine)Ni^III₂(1474011-52-3)
• EPA Substance Registry System: (4,4'-(di-tert-butyl)-2,2'-bipyridine)Ni^III₂(1474011-52-3)

Safety Data

• Hazardous Substances Data: 1474011-52-3(Hazardous Substances Data)

Upstream product

• 629-27-6 1-Iodooctane 
• 1474011-51-2 (4,4'-(di-tert-butyl)-2,2'-bipyridine)Ni^II(2-isopropylphenyl)(I) 

Downstream Products

• 605-39-0 2,2'-dimethyl-1,1'-biphenyl 
• 1474011-55-6 (4-4′-di-tert-butyl-2,2′-bipyridine)Ni^II(2-tolyl)(I) 

Relevant articles and documents

Mechanism and selectivity in nickel-catalyzed cross-electrophile coupling of aryl halides with alkyl halides

The direct cross-coupling of two different electrophiles, such as an aryl halide with an alkyl halide, offers many advantages over conventional cross-coupling methods that require a carbon nucleophile. Despite its promise as a versatile synthetic strategy, a limited understanding of the mechanism and origin of cross selectivity has hindered progress in reaction development and design. Herein, we shed light on the mechanism for the nickel-catalyzed cross-electrophile coupling of aryl halides with alkyl halides and demonstrate that the selectivity arises from an unusual catalytic cycle that combines both polar and radical steps to form the new C-C bond.