1474024-89-9Relevant academic research and scientific papers
Synthesis, structure, and conformational mobility of a vaulted trans-bis(o-aminophenolato)platinum(II) complex
Komiya, Naruyoshi,Takahashi, Koichi,Tanaka, Tomoya,Yoshida, Atsushi,Naota, Takeshi
, p. 659 - 664 (2013)
The synthesis, structure, and conformational mobility of a trans-bis(aminophenolato)platinum(II) complex bearing a dodecamethylene bridge, [Pt(L)] (1) [H 2 L = N,N′-Dimethyl-N,N′-bis(2- hydroxyphenylmethyl)dodecane-1,12-diamine] are described. The 2D NMR and X-ray diffraction analysis revealed that the complex has a reversed U -shaped syn conformation in the solution state, which is mainly due to steric congestion of the vaulted structure and hydrogen bonding at the bis[(o-aminomethyl)phenolato] coordination site, while the complex unit is packed in the crystalline state with Z-shaped anti-conformation due to highly regulated molecular arrangement by 3D CH-π and hydrogen bonding interactions.
